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Exploring the Mysteries of Metal Compounds

 

Irene Waller at the University of British Columbia in Vancouver uses a high energy laser to remove electrons from molecules in the gas phase, and then measures the electrons' kinetic energy. She is the first scientist in Canada to use this powerful technique, called negative-ion photoelectron spectroscopy. With it, she plans to learn more about the electronic structure of transition metal complexes, and to study the chemistry of compounds that contain several metals (so-called cluster complexes).


Working with both theory and practice, Melinda Gugelchuk of the University of Waterloo in Waterloo, Ont. Studies ways to spped up chemical reactions. She has a special interest in biologically important reactions that involve transition metals. Her calculations are expected to reveal how factors such as molecular shape, solvent effects, metal coordination, etc. influence the rates of these reactions.


Computation is also the tool used by Kathy Darvesh, of Mt. Saint Vincent University in Halifax. She is starting an ambitious research program to carry out calculations on reactions involving heavy metal atoms. She expects that her calculations will allow her to predict the shapes of molecules at equilibrium, as well as rates for important chemical reactions.

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